During His 40 days of fasting & praying in the Wilderness, Satan tempted Jesus: to make bread out of stones to relieve his own hunger; to jump from a pinnacle & rely on angels to break his fall (both Luke & Matthew have Satan quote Psalm 91:11–12 to indicate that God had promised this assistance); & to worship Satan in return for all the kingdoms of the world.
The temptation of making bread out of stones occurs in the desert setting where Jesus had been fasting. This temptation may have been Jesus' last, aiming towards his hunger. In response to Satan's suggestion, Jesus replies, "It is written: 'One does not live by bread alone, but by every word that proceeds from the mouth of God." (a reference to Deuteronomy 8:3)